Browsing by Author "Bachilo, S."

Now showing items 1-2 of 2

    • Pathways for photoinduced electron transfer in meso-nitro-phenyl-octaethylporphyrins and their chemical dimers 

      Knyukshto, V.; Zenkevich, E.; Sagun, E.; Shulga, A.; Bachilo, S. (1999)
      The photophysical properties of meso-nitro-phenyl-octaethylporphyrins and their dimers with electron-accepting NO₂ groups in the para-, meta- and ortho-positions of the phenyl ring were studied. For the ortho-NO₂ case in deaerated toluene at 295 K, strong fluorescence quenching is caused by the intramolecular electron transfer from the porphyrin S₁ state in the absence of phenyl ...
      2017-05-25

    • Unusual dynamic relaxation of triplet-excited meso-phenyl-substituted porphyrins and their chemical dimers at room temperatures 

      Knyukshto, V.; Zenkevich, E.; Sagun, E.; Shulga, A.; Bachilo, S. (1998)
      It has been found that for mono- and di-meso-phenyl-substituted octaethylporphyrin (OEPs), etioporphyrins, corresponding Zn complexes and OEP chemical dimers (with a meso-phenyl spacer) a drastic shortening of triplet lifetimes from a ms to μs timescale in deaerated toluene solutions at 295K takes place without any changes of the spectral-kinetic parameters of the S₀ and S₁ states. ...
      2017-05-25