Now showing items 1-5 of 5

    • Competition between electron transfer and energy migration in self-assembled porphyrin triads 

      Zenkevich, E. I.; Willert, A.; Bachilo, S. M.; Rempel, U.; Kilin, D. S.; Shulga, A. M.; Borczyskowski, C. von (2001)
      The photoinduced electron transfer (ET) and the energy migration (EM) processes have been studied in liquid solutions and polymeric (PMMA) films for the triads consisting of the Zn-octaethylporphyrin chemical dimer (the energy and electron donor, D) and dipyridyl substituted tetrapyrrole extra-ligands (porphyrins, chlorin, tetrahydroporphyrin) as the acceptors, A. On the basis ...
      2017-05-26
    • Electron transfer in porphyrin multimolecular self-organized nanostructures 

      Zenkevich, E. I.; Bachilo, S. M.; Shulga, A. M.; Rempel, U.; Willert, A.; Borczyskowski, C. von (1998)
      On the base of of covalent and non-covalent bonds nanoscale self-assembling multiporphyrin arrays with well-defined geometry, the controllable number of interacting components and their spectral and photophysical properties were formed. The deactivation of excited singlet and triplet states was studied using steady-state, time-resolved picosecond fluorescence (∆½≈30 ps) and ...
      2017-05-25
    • Photoinduced charge transfer via "Superexchange" mechanism in porphyrin triads with electron acceptors 

      Zenkevich, E. I.; Willert, A.; Borczyskowski, C. von (РИВШ, 2017)
      Zenkevich, E. I. Photoinduced charge transfer via "Superexchange" mechanism in porphyrin triads with electron acceptors / E. I. Zenkevich, A. Willert, C. von Borczyskowski // Квантовая электроника : материалы XI Международной научно-технической конференции, Минск, 13—17 ноября 2017 года / [редкол.: М. М. Кугейко (ответственный редактор) и др.]. – Минск : РИВШ, 2017. – С. 35-36.
      2021-06-28
    • Photoinduced electron transfer dynamics for self-assembled porphyrin arrays in solutions and films 

      Zenkevich, E. I.; Kilin, D. S.; Willert, A.; Bachilo, S. M.; Shulga, A. M.; Rempel, U.; Borczyskowski, C. von (2001)
      Electronic excitation energy deactivation in self-assembled porphyrin triads has been studied by the time correlated single photon counting technique as a function of the solvent polarity (toluene-acetone mixtures), temperature (77-350 K), and mutual spatial arrangement of the donor and acceptor subunits. The donor (Zn-octaethylporphyrin chemical dimer) fluorescence quenching ...
      2017-05-26
    • Self-assembled nanoscale photomimetic models: structure and related dynamics 

      Zenkevich, E. I.; Borczyskowski, C. von; Shulga, A. M.; Bachilo, S. M.; Rempel, U.; Willert, A. (2002)
      Using static and time-resolved measurements, dynamics of non-radiative relaxation processes have been studied in self-assembled porphyrin triads of various geometry, containing the main biomimetic components, Zn–porphyrin dimers, free-base extra-ligands (porphyrin, chlorin or tetrahydroporphyrin), and electron acceptors A (quinone or pyromellitimide). The strong quenching of the ...
      2017-05-26